Yes, It is Possible in eZee frontdesk. Kindly refer below screenshot for configuration of early checkIn and late checkout charges.
Step : 1 - Active options from eZee frontdesk configuration.
Open eZee frontdesk configuration >> Advance settings >> Rental.
Step : 2 - Set the charges per slab. Go to Configuration >> Others >> E.C.I / L.C.O slabs.
Screenshot : 1
Screenshot : 2